Solubility

1. Solubility of Various Compounds in Glycerol

Substance
Glycerol
Concentration
Weight
Temp.
()
Sol.in Part
per100 parts
of Solvent
Ref.
Alum
Ammonium carbonate
V
V
Ammonium chloride
Anisic aldehyde
Arsenic acid
Arsenious acid
Atropine
Atropine sulfate
V
Barium chloride
Benzoic acid
V
V
V
V
V
Benzyl acetate
Boric acid
V
Brucine
Calcium hydroxide
Calcium hypophosphite
V
Calcium oleate
Calcium sulfate
Calcium sulfide
Cinchonine
Cinchonine sulfate
Cinnamic aldehyde
Codeine hydrochloride
V
Copper acetate
Copper sulfate
Ethyl acetate
V
Ethyl ether
V
Eugenol
Ferrous sulfate
Guaiacol
V
Guaiacol carbonate
V
Iodine
Iodoform
lron and potassium tartrate
lron lactate
lron oleate
Lead acetate
V
V
Lead sulfate
Magnesium oleate
Mercuric chloride
Mercurous chloride
Mercurous cyanide
Morphine
Morphine acetate
Morphine hydrochloride
Novocaine
V
Oxalic acid
Pentaerythritol
Phenacetin
V
Phenol
V
Phenylethyl alcohol
Phosphorus
Potassium arsenate
Potassium bromide
V
V
Potassium chlorate
V
V
Potassium chloride
Potassium cyanide
Potassium iodate
Potassium iodide
V
V
Quinine
Quinine sulfate
V
Quinine tannate
V
V
Salicin
Salicylic acid
V
Santonin
Sodium arsenate
V
V
Sodium bi-borate
V
Sodium bicarbonate
Sodium tetraborate(borax)
Sodium carbonate(crystals)
Sodium chlorate
Sodium hypophosphite
V
Sodium pyrophosphate
Sodium sulfate(12HQO)
Stearic acid
V
Strychnine
Strychnine nitrate
Strychnine sulfate
Sulfur
Tannic acid
Tannin
Tartar emetic
Theobromine
V
Urea
Zinc chloride
Zinc iodide
Zinc sulfate
Zinc valerate
V
*
*
99.04
87.27
*
*
*
*
*
99.04
87.27
*
98.5
95.1
90
86.5
75
50
*
98.5
86.5
*
35
99.04
87.27
45
*
*
*
*
*
99.04
87.27
*
*
99.04
87.27
99.04
87.27
*
*
99.04
87.27
99.04
87.27
*
95
*
*
45
*
98.5
86.5
*
45
*
*
*
*
*
*
99.04
87.27
*
100
99.04
87.27
99.04
87.27
*
*
*
*
98.5
86.5
*
98.5
86.5
*
*
*
*
98.5
86.5
*
98.5
86.5
*
99.04
87.27
*
98.5
86.4
*
*
99.04
87.27
98.5
86.5
*
*
*
*
99.04
87.27
87.27
100
99.04
87.27
*
*
*
*
*
*
*
99.04
87.27
*
*
*
*
99.04
87.27
15
15
20
20
15
15
15
15
15
20
20
15
|
23
23
|
23
23
15
20
20
15
25
20
20
15
15
15
15
15
15
20
20
15
15
20
20
20
20
15
15
20
20
20
20
15
15
15
15
15
15
|
|
15
15
15
15
15
15
15
15
20
20
15
100
20
20
20
20
15
15
15
15
|
|
15
|
|
15
15
15
15
|
|
15
|
|
15
20
20
15
|
|
15
15
20
20
|
|
15
15
15
15
20
20
20
25
20
20
15
15
15
15
15
15
15
20
20
15
15
15
15
20
20
40
20
19.8
13.7
20.06
0.1
20
20
3
45.2
45.8
9.73
2
2.01
1.74
1.18
1.02
0.60
0.1
24.80
13.79
2.25
1.3
2.5
3.2
1.18
5.17
5
0.30
6.70
0.1
11.1
4.7
10
30
1.9
1.8
0.65
0.38
0.1
25
13.1
9.05
0.043
0.039
2
0.12
8
16
0.71
10
143
129.3
30.3
0.94
8
7.5
27
0.45
20
20
11.2
7.8
15.1
9.3
0.47
0.3
276.4
361.8
1.5
ca.O.25
50.13
25
17.15
20.59
3.54
1.03
1.32
3.72
31.84
1.9
39.72
50.70
58.27
0.47
1.32
0.72
0.25
2.8
2.45
12.5
1.63
0.985
6
50
64
44
111.15
89.36
8.06
60
98.3
20
32.7
42.2
9.6
8.1
0.089
0.066
0.25
4
22.5
ca.O.1
48.8
48.83
5.5
0.028
0.017
50
49.87
39.78
35.18
0.336
0.382
6
8
9
9
8
1
6
6
5
9
9
8
4
|
|
4
|
|
1
4
4
5
2
9
9
6
8
6
5
5
1
9
9
6
6
9
9
9
9
1
6
9
9
9
9
8
3
5
5
8
8
4
4
8
6
8
5
5
5
5
5
9
9
6
Anon.
9
9
9
9
1
8
8
6
4
4
8
4
4
8
8
5
8
4
4
8
4
4
5
9
9
5
4
4
5
8
9
9
4
4
8
8
8
5
9
9
9
10
9
9
5
5
5
8
6
8
5
9
9
5
8
8
8
9
9
* Glycerol concentration not specified, probably 95 to 100 per cent.

  1. : "Allen's Commercial Organic Analysis",Fourth ed, P461, P.Blakiston's Son & Co., Philadephia(1923).
  2. : Cameron,F.K.,and Patten,H.E.,J.Phys.Chem.,15,67-72(1911).
  3. : Chiaria,P.,Giorn.farm.chim.,66,94-96(1917).
  4. : Holm,K.,Pharm.Weekblad,58,860-862(1921); ibid.,1033-1037(1921).
  5. : Lawrie,J.W.,"Glycerol and the Glycols",P232,New York,The Chemical Catalog Co.Inc. (Reinhold Publishing Corp.) 1928.
  6. : Lewkowitsch,J.,"Chemical Technology and Analysis of Fats and Waxes",Sixth ed.,P254, London, MacMillan & Co.Ltd.(1921).
  7. : Noble,M.V.,and Garrett, A.B.,J.Am.Chem.Soc.,66,231-235(1944).
  8. : Ossendovsky,A.M.,J.Russ.Phys.Chem.Soc.,37,1071(1906). Through Mac Ardle,D.W.,"The Use of Solvents in Organic Chemistry",P80, New York,D.van Nostrand Co.Inc.(1925).
  9. : Roborgh,J.A.,Pharm.Weekblad,64,1205-1209(1927).
  10. : Schnellbach,W.and Rosin.J.,J.Am.Pharm.Assoc.,18,1230-1235(1929).


2. Solubility of Sodium Chloride in Glycerol

Solution
Glycerol before
saturation (%)
g NaCl per
100g solution at 25
A
B
C
D
E
F
G
H
I
J
10.45
20.30
30.45
40.15
50.82
60.10
69.90
75.83
86.22
95.64
24.5
22.5
20.5
18.4
16.2
14.3
12.2
11.1
9.4
8.1

Ref. : Carr,A.R.,Townsend,R.E.and Badger,W.L.,Ind.Eng.Chem.,17,643-646(1925).